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Article
Publication date: 1 January 2016

Ramazan Kahraman, Huseyin Saricimen, Zuhair Omar Malaibari and Md Abdur Rauf

The purpose of this study was to investigate the performances of two inhibitors in controlling corrosion of steel products in industrial and marine atmosphere.

Abstract

Purpose

The purpose of this study was to investigate the performances of two inhibitors in controlling corrosion of steel products in industrial and marine atmosphere.

Design/methodology/approach

Corrosion rates were determined by weight loss measurements. At certain periods of atmospheric exposure, the (disc shape) specimens were retrieved and studied by scanning electron microscopy and energy-dispersive spectrometry surface analysis techniques.

Findings

Both inhibitors were effective against corrosion of steel in the early stages of the atmospheric exposure (for about two months). With further exposure to the atmosphere, their inhibition effectiveness deteriorated and was totally lost within four months. Analysis of the specimens before exposure showed that the inhibitor film was thin for both treatments, and the unexposed treated surface for both inhibitors appeared similar to the untreated unexposed specimen surface. Characterization of the specimens at different exposure periods showed fewer corrosion blisters on dicyclohexylamine nitrite- and sodium benzoate-treated surfaces than on untreated specimens.

Originality/value

The objective of this study was to characterize the surfaces of the steel products produced locally during their exposure to the industrial and marine atmosphere of the Arabian Gulf region after being treated by sodium benzoate and dicyclohexylamine nitrite in controlling the corrosion of local mild steel products. According to the literature review, this study is original and will add value to the studies of inhibition of steel corrosion under similar environments.

Details

Anti-Corrosion Methods and Materials, vol. 63 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 September 2013

Zuhair Malaibari, Ramazan Kahraman and Abdur Rauf

The purpose of this study was to investigate the performances of three inhibitors in controlling corrosion of local mild steel products in distilled water and a simulated salt…

Abstract

Purpose

The purpose of this study was to investigate the performances of three inhibitors in controlling corrosion of local mild steel products in distilled water and a simulated salt solution.

Design/methodology/approach

Corrosion inhibition of mild steel was investigated using electrochemical techniques. Untreated and inhibitor treated specimens were fully immersed in two test solutions, distilled water and the simulated solution of 2.0 wt.% NaCl and 1.0 wt.% Na2SO4.

Findings

During full immersion in the simulated salt solution, sodium dihydrogen orthophosphate was not effective at all, resulting in even higher corrosion rates than that of the untreated specimens. Sodium benzoate was effective for three days only. Dicyclohexylamine nitrite was the most effective of them all, keeping its effectiveness for as much as 20 days. When the specimens were immersed in distilled water, all three inhibitors were effective during the 60 days of immersion while dicyclohexylamine nitrite and sodium benzoate treated specimens performed better than those treated with sodium dihydrogen orthophosphate.

Originality/value

The objective of this research was to investigate the performances of three inhibitors – sodium dihydrogen orthophosphate (inorganic) at 10 mM concentration, dicyclohexylamine nitrite (organic) and sodium benzoate (organic) at 100 mM concentration – in controlling the corrosion of local mild steel products fully immersed in two test solutions, distilled water and the simulated salt solution. All three inhibitors are film forming and anodic type inhibitors. According to the authors' literature review, this study is original and will add value to the studies of inhibition of steel corrosion under similar environments.

Details

Anti-Corrosion Methods and Materials, vol. 60 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

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